72 Hf Hafnium 178.492

Hafnium

TRANSITION METAL
Bohr Model: Electrons arranged in energy shells around the nucleus.

Hafnium is a chemical element with symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1923, making it the penultimate stable element to be discovered (rhenium was identified two years later).

Quick Facts

Atomic Number 72
Period 6
Group 4
Phase Solid
Appearance steel gray
About Transition Metals

Transition metals are elements with partially filled d-orbitals. They are hard, have high melting points, and often form colored compounds.

History

Discovered By Dirk Coster
Named By Unknown

Physical Properties

Atomic Mass 178.492
Density 13.31 g/L
Molar Heat 25.73 J/(mol·K)
Phase Transition (Melting & Boiling Points)

Hafnium melts at 2506 K and boils at 4876 K.

Atomic Properties

Electron Config [Xe] 4f14 5d2 6s2
Electronegativity 1.3
Electron Affinity 17.18 kJ/mol
Ionization Energy 658.5 kJ/mol
Orbital Filling Diagram
This diagram visualizes electron configuration according to the Aufbau principle and Hund's rule. Boxes represent orbitals (s, p, d, f), while arrows indicate electrons with spin up or down. Electrons fill lower energy levels first and occupy orbitals singly before pairing.
Emission Spectrum Emission spectrum of Hafnium

Photograph

Image of Hafnium Source: Wikipedia

External Resources

Study Guide

Atomic Number

The number of protons in the nucleus, which defines the element.

Atomic Mass

The average mass of an atom, including protons and neutrons.

Electronegativity

A measure of how strongly an atom attracts electrons in a bond.

Ionization Energy

The energy required to remove an electron from an atom.

Electron Config

The arrangement of electrons in the atom's energy shells.